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relaxation. The stress decreased gradually to a new plateau value of 0.20 MPa in ca. 70 min, which was related to the equilibrium state of the cis-trans thermal isomerization. This stress development and relaxation triggered by UV light was repeated for three cycles. In the latter two cycles, the stress curves were almost the same, demonstrating that the stress development and relaxation in response to UV light are reversible and reproducible.

(4.3.10) ad = -V8 K7csinh ( ^ ) (4.3.11)

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GS1 - 128 is an application standard of the GS1 implementation using the Code 128 barcode ... integer divided by 10 y . For example, a net weight of 22.7 kg could be coded as 3101 000227, 3102 002270, 3103 022700, or 3104 227000.

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Thus, for water and a temperature of 25 C, after substitution for the constants, when concentrations are expressed in moles per cubic decimetre, it follows that ad = 11.72c"2 sinh (19.46z02), [iC cm"2. The quantity a d expresses the total charge per square centimetre in the diffuse layer. If no

Stress (MPa)

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216 specific adsorption occurs, ie if no ions are present within the compact part of the double layer, then ad = a(l) = a(m) For small (f)2 RT/F, in Eq (4311) all the terms in the infinite series for the hyperbolic sine except the first can be neglected, so that (4312) where Lu = {eRTl2c)ml2F is the Debye length (see Eq 1317) Under these conditions, the diffuse layer acts as a plate capacitor with charge ad and thickness LD The differential capacity of the diffuse layer is defined by the relationship C d = dajd(t>2 According to this definition we obtain, from Eq (4311), (4313) The total differential capacity can be either measured directly (see Section 44) or calculated from Eq (4225).

0.1 UV on 0 0 0.1 2 4 6 8 10 Time (103 S) 12 14 16 18 20

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Because d[0(m) - 0(1)] = d p , the differential capacity of the diffuse layer Cd can be calculated from Eq (4313), with substitution of the potential </)2 from Eq (4311) As for zero specific adsorption qd = q(m), the potential <f>2 is given by the relationship " 2RT A sinrT1 ' zF RT <4-3-i4> Figure 44 depicts the dependence of (f)2 on E - Epzc (the 'rational potential') for various electrolyte concentrations The charge density on the electrode a(m) is mostly found from Eq (4224) or (4226) or measured directly (see Section 44) The differential capacity of the compact layer Cc can be calculated from Eq (431) for known values of C and Cd.

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Figure 13.27. Stress development and relaxation of the photoresponsive gel lms (thickness: 225 nm) in response to alternating UV light and dark exposure.

It follows from experiments that the quantity Cc for surface inactive electrolytes is a function of the potential applied to the electrode, but is not a function of the concentration of the electrolyte Thus, if the value of Cc is known for a single concentration, it can be used to calculate the total differential capacity C at an arbitrary concentration of the surface-inactive electrolyte and the calculated values can be compared with experiment This comparison is a test of the validity of the diffuse layer theory Figure 45 provides examples of theoretical and experimental capacity curves for the non-adsorbing electrolyte NaF Even at a concentration of 0916 mol dm"3, the Cd value is not sufficient to permit us to set C Cc o(m) v '.

However, in the rst cycle, there was a residual stress of 020 MPa that was not recovered completely by the cis-trans thermal isomerization in the dark UV light can cause the condensation of sol gel materials (Clark et al, 2000), and in this case, the UV light irradiation in the rst cycle caused the further condensation of the photoresponsive gel framework, which induced tensile stress in the lm Such stress from the chemical change is not reversible and not recoverable However, the cis-trans thermal isomerization of azobenzene derivatives at room temperature is reversible though slow (kE10 5 s 1, t1/2E104 s), requiring a very long time for a complete recovery of the cis-trans thermal isomerization In the experiment, the interval of the UV light off is ca 70 min, not long enough for the complete recovery of the trans-cis conformational change of the azobenzene ligands.

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In another experiment on a thicker lm (376 nm in thickness) prepared using the same gel solution, a similar phenomenon was observed The maximum tensile stress under UV light irradiation is 1 Mpa, and the residual stress in the rst cycle is 032 MPa; that is, 32% of the stress was not relaxed, which is comparable with that of the former sample (34%) with a thinner thickness The photoresponsive stress change of the BSUA-derivatized gel lms can be explained by the dimensional change accompanying the photoisomerization of the azobenzene ligand Under UV irradiation, the trans-cis isomerization of the azobenzene ligands causes the shrinkage of the exible gel network because of the shorter molecular length of the cis conformation than the trans conformation, which bends the silicon substrate upwardly and generates a tensile stress on the substrate.

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