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Fig. 4.4 The dependence of the potential difference in the diffuse layer on the difference E Epzc (the rational potential) for various concentrations of the surface inactive electrolyte KF. (According to R. Parsons)

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According to Eq. (4.3.13) the differential capacity of the diffuse layer Cd has a minimum at 4>2 = 0, i-e. at E = Epzc. It follows from Eq. (4.3.1) and Fig. 4.5 that the differential capacity of the diffuse layer Cd has a significant effect on the value of the total differential capacity C at low electrolyte concentrations. Under these conditions, a capacity minimum appears on the experimentally measured C-E curve at E = Epzc. The value of Epzc can thus be determined from the minimum of C at low electrolyte concentrations (millimolar or lower). This theory of the diffuse layer is satisfactory up to a symmetrical electrolyte concentration of 0.1mol-dm~ 3 , as the Poisson-Boltzmann equation is valid only for dilute solutions. Similarly to the theory of strong electrolytes, the Gouy-Chapman theory of the diffuse layer is more readily applicable to symmetrical rather than unsymmetrical electrolytes.

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At the photostationary state, the ratio between the two isomers (trans:cis) reaches a maximum, thus the stress stays at the maximum level When the UV light is switched off, the thermal cis-trans isomerization of the azobenzene moieties relieves the tensile stress..

The structure of the compact layer depends on whether specific adsorption occurs (ions are present in the compact layer) or not (ions are absent from the compact layer). In the absence of specific adsorption, the surface of the electrode is covered by a monomolecular solvent layer. The solvent molecules are oriented and their dipoles are distorted at higher field strengths. The permittivity of the solvent in this region is only an operational quantity, with a value of about 12 at the Epzc in water,

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The azobenzene-modi ed mesoporous silica materials are ideal platforms to study photocontrolled transport behavior because of their easy fabrication, easy integration into nanodevices, and well-controlled pore connection, pore dimension, and surface chemistries. To date, all the related work reported in the literature has dealt with numerous nanochannels. It will be a milestone if we can study the photocontrolled transport behavior of a few nanochannels or even a single nanochannel with azobenzene-modi ed pore surfaces. However, signi cant engineering problems exist in the fabrication of such a single-channel device. On the one hand, an azobenzene-modi ed single channel device mimics both the structure and chemistry of nature ion channels, which have intricate applications in stochastic sensing, molecular recognition, DNA sequencing, and chemical and bioweapon detection because of the ultrasensitive detection of matter passage through the channel. On the other hand, the photoisomerization of the azobenzene moieties can regulate the diffusion rate of molecules and ions through the

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Fig. 4.5 Dependence of the differential capacity C (JUF cm"2) of a mercury electrode in 0.916 M NaF (O) and in 1 mM NaF ( ) on the electrode potential (vs. NCE). The curves correspond to calculations according to Eqs (4.3.1) and (4.3.13); curve 1 as Cc, curve 2 as C = (1/CC+ 1/Cd)~\ (According to D. C. Grahame)

channel at molecular scale, which opens a new era for sensitive reactions requiring minute amounts of reactants. Other than the fabrication of single-channel devices, new azobenzene-containing organosilanes must be synthesized to make the photoresponsive nanoporous materials more suitable for applications in nano uidic devices, molecular gates, and controlled releases. The reported azobenzene-containing organosilanes, that is, TSUA, have exible spacer groups between the trialkoxysilyl and rigid azobenzene groups. After the azobenzene groups are anchored on the pore surfaces, they oat around because of the exibility of the spacer groups, and correspondingly compromise the extent of the pore size change triggered by light stimuli. Thus, it is of particular interest to synthesize new azobenzene-containing organosilanes with rigid pendant groups, such as organosilane with an azobenzene pendant group directly bonded to a triethoxysilyl group. Furthermore, the organosilanes with multiple azobenzene groups in series are capable of a larger change in the molecular dimension and effective pore size after the assembly on the pore surfaces, enabling better control of mass transport through the corresponding photoresponsive nanocomposite lms.

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