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The adsorbed ions (anions are considered) are located at the inner Helmholtz plane In describing the distribution of the electrical potential in the compact layer, the discrete structure of the charge in this layer must be considered, rather than continuous charge distribution, as was pointed out by O A Essin, B V Ershler, and D C Grahame The inner Helmholtz plane is no longer an equipotential surface As demonstrated by A N Frumkin, the potential at the centre of the adsorbed ion plays the greatest role in the determination of the adsorption energy of ions Ershler called this the micropotential More exactly, it is the potential at the point where the given ion is adsorbed after subtracting the value of the coulombic potential formed by this ion.

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Mechau N, Saphiannikiva M, Neher D 2005 Dielectric and mechanical properties of azobenzene polymer layers under visible and ultraviolet irradiation Macromolecule 38:3894 Montal M, Mueller P 1972 Formation of bimolecular membranes from lipid monolayers and a study of their electrical properties Proc Natl Acad Sci USA 69:3561 Natansohn A 1999 Azobenzene containing materials Weinheim: Wiley p 165 Nguyen TD, Tseng HR, Celestre PC, Flood AH, Liu Y, Stoddart JF, Zink JI 2005 A reversible molecular valve Proc Natl Acad Sci USA 102:10029 10034 Nguyen TD, Leung KCF, Liong M, Pentecost CD, Stoddart JF, Zink JI 2006 Construc tion of a ph driven supramolecular nanovalve Org Lett 8:3363 3366 Nicole L, Boissiere C, Grosso D, Quach A, Sanchez C 2005 Mesostructured hybrid organic inorganic thin lms J Mater Chem 15:3598 3627 Ogawa M, Kurodacd K, Moric JI 2000 Aluminium containing mesoporous silica lms as nano vessels for organic photochemical reactions.

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If the solution is considered to be a good electric conductor, then it is useful to introduce the concept of electric image induced in an arbitrary conductor when a point charge is located close to its surface The electric image has the opposite charge with the same absolute value as the point charge and is situated inside the conductor at the same distance from the surface as the original charge on the other side of the interface The discrete negative charges induce a positive image charge in the solution, which is reflected on the outer Helmholtz plane (Fig 46) The actual electric cloud of ions behind the outer Helmholtz plane is compressed so that it can be replaced by this electric image The introduction of the concept of the micropotential permits derivation of various expressions for the potential difference produced by the adsorbed anions, ie.

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Chem Commun:2441 2442 Patterson BC, Hurst JK 1993 Pathways of viologen mediated oxidation reduction reactions across dihexadecyl phosphate bilayer membranes J Phys Chem 97: 454..

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for the potential difference between the electrode and the solution during specific adsorption of ions It has been found that, with small coverage of the surface by adsorbed species, the micropotential depends almost linearly on the distance from the surface The distance between the inner and outer Helmholtz planes is denoted as xx_2 and the distance between the surface of the metal and the outer Helmholtz plane as x2 The micropotential, ie the potential difference between the inner and.

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Fig. 4.6 The adsorbed anion A induces a positive charge excess at the outer Helmholtz plane, which can be represented as its image A'. The plane of imaging is identical with the outer Helmholtz plane. (According to B. B. Damaskin, O. A. Petrii and V. V. Batrakov)

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