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The surface of a solid electrode is not homogeneous; even an apparently smooth surface as observed in an optical microscope contains corners and edges of the crystal structure of the metal and dislocations, i.e. sites where the regular crystal structure is disordered (see Section 5.5.5). Adsorption on a physically heterogeneous surface differs from that on a physically homogeneous surface. The heat of adsorption and Gibbs energy of adsorption differ from one site to another, and the sites with the lowest Gibbs energy of adsorption are occupied first. M. Temkin derived an adsorption isotherm considering a physically heterogeneous surface. The derivation was based on the assumption of a continuously heterogeneous surface, where the free energy of adsorption per unit fraction dS of a unit surface area increases linearly with increasing S (the unit surface is divided into elements dS, each of which is considered to be homogeneous):

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RDLC reports, created by the Visual Studio ReportViewer control based on Report Definition Language Client Side, are local reports and completely run in local ...

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Supramolecular azobenzene materials (Continued) birefringence, 58f H bonding, 55, 56, 57f, 58f intractions, 55f ISA complexes and, 67 68 surface relief gratings, 68 82, 70f, 79f, 80f AFM image of, 76f application of, 74 holographic irradiation, 74 75 ionic interaction, 73 kinetics in ionic complexes, 75f noncovalent interactions, 72 stability of, 76 77, 77f surface modulation, 71 Supramolecular cooperative motion (SMCM), 411 Surfacant directed self assembly (SDSA), 468 Surface acoustic wave (SAW), 472 Surface grated LC polymer, 280 282, 281f Surface mass transport, in azobenzene polymers, 145 159 Surface relief grating (SRG), 27, 49, 50, 51, 52, 68 82, 145, 146f, 152, 153, 154 155, 158, 160 161, 164, 166, 193, 305, 305f, 306, 380, 438 441 Surfactant silica nanohybrids, 275 277, 276f Synthesis, of azo polymers, 179 182

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Triblock polymer (ABA), 218 Tunable diffraction gratings coupled mechanical effects, 369 371, 370f, 371f de nition of, 365, 377f dynamics of, 375 381, 379f elastic diffraction gratings, 372 375, 372f, 374f, 375f, 376f electrically tunable gratings liquid crystals use, 381 382 in photosensitive gels, 382 387, 383f, 385f electrical switching, 387 389, 387f, 389f mechanically tunable, 365 366, 366f mechanism of, 375 381, 378f, 379f optical effects, 369 371, 370f, 371f optically tunable dynamic holographic, 389 391, 390f, 391f in polymer LCs, 391 400 switchable, 400 404, 402f, 403f recording of, 363 365, 364f thermoplastic elastomers, 367 369, 368f

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where AGads is the value of the Gibbs adsorption energy for S = 0, A^ads + a for S = 1. If it is assumed that adsorption proceeds according to the Langmuir isotherm on each homogeneous, planar element, then the covered fraction of planar element dS is

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Sun ST, Gibbons WM, Shannon PJ 1992 Alignment of guest host liquid crystals with polarized laser light Liq Cryst 12(5):869 874 Suzuki I, Sato K, Koga M, Chen Q, Anzai J I 2003 Polyelectrolyte layered assemblies containing azobenzene modi ed polymer and anionic cyclodextrins Mater Sci Eng C 23(5):579 583 Tanaka K, Tateishi Y, Nagamura T 2004 Photoisomerization of azobenzene probes tagged to polystyrene in thin lms Macromolecules 37(22):8188 8190 Tang Z, Kotov NA, Magonov S, Ozturk B 2003 Nanostructured arti cial nacre Nat Mater 2:413 418 Tawa K, Knoll W 2002 Out of plane photoreorientation of azo dyes in polymer thin lms studied by surface plasmon resonance spectroscopy Macromolecules 35(18):7018 7023 Teraguchi M, Masuda T 2000 Synthesis and properties of polyacetylenes having azobenzene pendant groups Macromolecules 33(2):240 242 Thierry B, Winnik FM, Merhi Y, Tabrizian M 2003.

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Nanocoatings onto arteries via layer by layer deposition: toward the in vivo repair of damaged blood vessels J Am Chem Soc 125(25):7494 7495 Tokuhisa H, Yokoyama M, Kimura K 1994 Photoresponsive ion conducting behavior of polysiloxanes carrying a crowned azobenzene moiety at the side chain Macromolecules 27(7):1842 1846 Toutianoush A, Tieke B 1998 Photoinduced switching in self assembled multilayers of azobenzene containing ionene polycations and anionic polyelectrolytes Macromol Rapid Commun 19(11):591 595 Toutianoush A, Saremi F, Tieke B 1999 Photoinduced switching in self assembled multilayers of ionenes and bolaamphiphiles containing azobenzene units Mater Sci Eng C C8 C9:343 352 Tsuchiya S 1999 Intramolecular electron transfer of diporphyrins comprised of electron de cient porphyrin and electron rich porphyrin with photocontrolled isomerization J Am Chem Soc 121(1):48 53 Tsutsumi N, Yoshizaki S, Sakai W, Kiyotsukuri T 1996 Thermally stable nonlinear optical polymers MCLC S&T, Section B: Nonlinear Optics 15(1 4):387 390.

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Uznanski P, Pecherz J 2002 Surface plasmon resonance of azobenzene incorporated polyelectrolyte thin lms as an H+ indicator J Appl Polym Sci 86(6):1459 1464 Uznanski P, Kryszewski M, Thulstrup EW 1991 Linear dichroism and trans cis photo isomerization studies of azobenzene molecules in oriented polyethylene matrix Eur Polym J 27(1):41 43 Van Cott KE, et al 2002 Layer By layer deposition and ordering of low molecular weight dye molecules for second order nonlinear optics Angew Chem Int Ed 41(17):3236 3238 Villavicencio O, McGrath DV 2002 Azobenzene containing dendrimers Advances in Dendritic Macromolecules 5:1 44 Viswanathan NK, et al 1999 Surface relief structures on azo polymer lms J Mater Chem 9(9):1941 1955 Voinova MV, Jonson M 2004 Electronic transduction in model enzyme sensors assisted by a photoisomerizable azo polymer Biosens Bioelectron 20(6):1106 1110 Vollmer MS, Clark TD, Steinem C, Ghadiri MR 1999 Photoswitchable hydrogen bonding in self organized cylindrical peptide systems.

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