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The uniformity of the photoreaction and rebuilding of the initial state at the molecular level guarantee the complete reversibility of the processes Note that an important advantage of azobenzenes is that both photoisomerization processes take place with high quantum yields and without further side reactions Therefore, in contrast to most other chromophores, a number of isomerization cycles can be carried out without material destruction All these effects have been widely addressed in the literature Since the pioneer work on photoinduction of optical anisotropy in photosensitive organic materials (Weigert, 1929), the dynamic photoorientation in azobenzene-containing viscous solutions (Makushenko et al, 1971) and dye-polymer blends (Gibbson et al, 1991; Todorov et al, 1984), and the stable anisotropy in functionalized glassy polymers (Eich et al, 1987) have been studied Typical optical applications of the photoinduced order include polarization elements (Petrova et al.

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The exponential is expanded in a series and, except for unity, only the linear term is retained (this is permissible only when the electrostatic energy e \Zi\pk\ is small compared with the energy of thermal motion kT):

15

(Here SA^z, = 0 because of the electroneutrality condition.) Equation (1.3.10) is substituted into Eq. (1.3.6) and the Laplace operator is expressed in polar coordinates (for the spherically symmetric problem):

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R2 is the same value as X. Thus, the outcome of a sequence of two XORs using the same value produces the original value. To see this feature of the XOR in ...

, 2003), diffraction optical elements (Martinez-Ponce et al, 2004), waveguides (Karimi-Alavijeh et al, 2008; Luo et al, 2007), optical storage (Nedelchev et al, 2003; Hagen and Bieringer, 2001; Sabi et al, 2001), all-optical switching (Luo et al, 2005), multiplexing (Ilieva et al, 2005), alignment of liquid crystals (Ichimura, 1996; Ichimura et al, 1994) and bulk alignment of liquid crystalline polymers (Zen et al, 2002; Rosenhauer et al, 2001; Han et al, 2000; Fischer et al, 1997; Stumpe et al, 1991), and orientation of further functional groups in liquid crystalline (LC) polymers (Rosenhauer et al, 2005) Repeated E Z isomerization may also result in a translation motion of the molecules This motion becomes manifested on spatially inhomogeneous irradiation The phenomenon has been known as a light-driven mass transport or, with.

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where kx and k2 are integration constants determined from the boundary conditions. If r ><*>, then t/^ >0, from which it follows that k2 = 0. The constant kx is determined by substitution of the expression for ipk into Eq. (1.3.10) for p. As the electroneutrality of the ion-ionic atmosphere system is required, the integration of the space charge around the central ion over the whole volume of the solution yields a charge of the same magnitude and of the opposite sign to that of the central ion. The volume element dV is

regard to optical applications, a light-induced formation of surface relief gratings (SRG) (Kim et al, 1995; Rochon et al, 1995) It implies an undulation of a lm surface upon irradiation with the spatially modulated light Such all-optical deformation is a quite unexpected phenomenon as it takes place in the solid lms below glass transition temperature The induced deformation is thermally and light reversible Another peculiarity of the process is its polarization selectivity: the mass transport is effective only in the direction in which the light electrical eld vector is modulated Currently, it is accepted in the literature that the repeated E Z isomerization is a necessary condition for this process The nature of a driving force is still not understood Several models have been proposed to describe the mechanism responsible for the surface relief formation but none can explain all observed effects.

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32 expressed in polar coordinates as dV = 4jrr2 dr. Thus,

The conclusion is dif cult, as the phenomenon has been reported in a variety of materials where not only different chromophores are used but also the materials properties differ drastically The question of the interin uence of molecular orientation and their translation motion remains unclear too More detailed explanations on the suggested mechanisms may be found in the original works (Saphiannikova and Neher, 2005; Baldus and Zilker, 2001; Bublitz, 2001; Fukuda et al, 2001b; Kumar et al, 1998; Le n et al, 1998; Pedersen et al, 1998; Barrett et al, 1996) and numerous reviews (Oliveira et al, 2005; Natansohn and Rochon, 2002; Yager and Barrett, 2001; Viswanathan et al, 1999) Formation of SRG is also addressed in 4 of this book and in Section 23 of this chapter All-optical formation of SRG has attracted much attention because of its potential for applications.

(1.3.13)

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