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Electrolyte Interface, Vol. 33, Lecture Notes in Chemistry, Springer-Verlag, Berlin, 1983. Mittal, K. L. (Ed.), Surfactants in Solution, Vols 1-3, Plenum Press, New York, 1984. Parsons, R., Structural effect on adsorption at the solid metal/electrolyte interface,

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et al, 2000; Shirota et al, 1998; Klima and Waniek, 1957) If the crystallization can be suppressed, the induction of anisotropy is possible in lms of lowmolecular-weight azobenzene derivatives (Fig 22) Surprisingly, SRG formation in a single crystal of 4-(dimethylamino)azobenzene was reported (Nakano et al, 2002) Low-molecular-weight glass-forming systems are an alternative to functionalized polymers (Tanino et al, 2007; Ishow et al, 2006; Presnyakov et al, 2006; Shirota, 2005; Ando et al, 2003; Chigrinov et al, 2002, 2003; Nakano et al, 2002; Perschke and Fuhrmann, 2002; Stracke et al, 2000; Utsumi et al, 2000; Shirota et al, 1998; Klima and Waniek, 1957) Sterically hindered bulky azobenzenecontaining molecules are a new family of functionalized materials that form amorphous lms by spin coating and vacuum deposition without any dilution of the system.

J. Electroanal. Chem., 150, 51 (1983).

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Such materials are free from polymer chains and any restricting entanglement of the backbone The results indicate that the existence of a polymer chain is not a necessary condition for induction of anisotropy and SRG formation The bulky structure of the molecules is a necessary condition to prevent the crystallization and ensure lm-forming properties Moreover, the glass transition of the materials is rather low, leading to low stability of the photoinduced structures As in the case of polymers, the alternative use of lowmolecular-weight glasses is also restricted by their speci c design and complicated synthesis The bulky structure restricts the inducible anisotropy In addition to amorphous glasses, there is one example for low-molecular-weight liquid crystalline glass-forming material (Stracke et al, 2000) Interestingly, that anisotropy and SRG, photoinduced in the glassy state of spin-coated lms at room temperature, were ampli ed by annealing in the mesophase.

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Parsons, R., Inner layer structure and the adsorption of organic compounds at metal electrodes, 7. Electroanal. Chem., 29, 1563 (1984). Reeves, R., The double layer in the absence of specific adsorption, CTE, 1, 83 (1980). Schmickler, W., A jellium-dipole model for the double layer, J. Electroanal. Chem., 150, 19 (1983). Vetter, K. J., and J. W. Schultze, Potential dependence of electrosorption equilibria and the electrosorption valence (in German), Ber. Bunsenges., 76, 920 (1972). Void, R. D., and M. J. Void, Colloid and Interface Chemistry, Addison-Wesley Publishing Company, Reading, Mass., 1983. Vorotyntsev, M. A., and A. A. Kornyshev, Models for description of collective properties of the metal/electrolyte contact in the electrical double-layer theory,

Elektrokhimiya, 20, 3 (1984).

Industrial application of photoinduced anisotropy or light-induced SRG formation requires ful lling of a number of additional parameters At rst the photochromic material has to be transferred in lms of good optical quality This can be achieved using different materials as discussed above and by different methods of lm preparations, such as spin coating, doctor blading, Langmuir Blodgett, or layer-by-layer (LbL) techniques In addition to the basic effects, a number of further requirements become important, such as the easy processing and handling of the lms Especially lm-forming properties, use of good and environmental solvents, restriction of crystallization and aggregation, good optical quality of the lms before and after induction, stability of the photoinduced effects, and, of course, the price of the materials are very important requirements for any application Moreover, the matrix can introduce speci c properties such as liquid crystallinity or further functionalization.

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Of the quantities connected with the electrical double layer, the interfacial tension y, the potential of the electrocapillary maximum pzc , the differential capacity C of the double layer and the surface charge density q(m) can be measured directly. The latter quantity can be measured only in extremely pure solutions. The great majority of measurements has been carried out at mercury electrodes.

Therefore, there is still a challenge to nd low cost systems capable of effective light-induced orientation and SRG formation The supramolecular chemistry with its variety of intermolecular interactions can be seen as exactly right strategy in design of functional materials According to the broad de nition by Lehn (1995), supramolecular chemistry is chemistry beyond the molecule It is the chemistry of intermolecular bonds forming supramolecular complexes or phases It may be divided into broad, partially.

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