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TSUA and BSUA were synthesized using isocyanato amino coupling reactions (Fig. 13.1) and characterized using several methods, including elemental analysis, nuclear magnetic resonance (NMR) spectra, and Fourier transform infrared (FTIR) spectroscopy (Liu, 2004). For the synthesis of TSUA compound, hexane was added after the reaction and the solution was cooled to 201C. Shiny needlelike orange crystals precipitated from the solution. The yield was W80%. The BSUA compound, a needlelike yellow solid, precipitated from the solution after re uxing the solution for 24 h under room light. The BSUA yield was W90%. UV/visible spectroscopy was used to investigate the reversible photo and thermal isomerization behaviors of TSUA and BSUA in solution (Fig. 13.2). For TSUA compound, emax was estimated to be 2.59 104 M 1 cm 1 on the basis of absorption band at 362 nm (the p p* transition of the trans isomer). UV irradiation with an Hg arc lamp (lmax = 350 nm) decreased the intensity of the 362-nm band and slightly increased the intensity of the 450-nm band, which is attributed to the n p* transition of the cis isomer. A photostationary state was reached within ca. 10 min. Exposure to room light caused the reverse cis-trans isomerization. Extended room light exposure (12 h) increased the trans isomer to ca. 96%. The cis2trans isomerization process was observed to be reversible over three cycles. In a detailed study, the rst-order kinetic constant of the cis-trans isomerization under room light exposure was estimated to be 1.75 10 4 s 1 for TSUA in ethanol solution at room temperature. Similar photoisomerization was observed for the BSUA compound in THF solution. UV irradiation (lmax = 350 nm) decreased the intensity of the 378-nm band (the p p* transition) and slightly increased the intensity of the 470-nm band (the n p* transition attributed

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3.2.5 Organic redox electrodes Quinhydrone, a solid-state associate of quinone and hydroquinone, decomposes in solution to its components. The quinhydrone electrode is an example of more complex organic redox electrodes whose potential is affected by the pH of the solution. If the quinone molecule is denoted as Ox and the hydroquinone molecule as H2Red, then the actual half-cell reaction Ox + 2e * Red2" (3.2.29) is accompanied by reactions between the hydroquinone anion Red2" and the solvent. Hydroquinone is a weak dibasic acid, with the dissociation constants

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As the prices of PCs dropped, demand continued to climb. With the power of the computer available to the general public, the need to share information became paramount. Another major event that would change computing forever was in the works. The popular use of the Internet grew exponentially in the 1990s and across the turn of the century (Y2K), surpassing all expectations. The Internet was created in 1969 as part of a project of the U.S. Department of Defense. Originally known as ARPANET (Advanced Research Projects Agency Network), it linked four computer sites at various universities and research centers and was used by scientists. Its usage grew to universities around the world throughout the 1970s, making it an international network, based on the TCP/IP protocol. As consumer products evolved to simplify access to the Internet, users in the general population discovered the power of using the Net. With the addition of the World Wide Web interface in 1990 which delivered web pages containing text, pictures, audio, and video more information began to appear and the Internet became a mainstay of both consumer and corporate communications. Companies like AOL, Google, Yahoo, and MSN sprung up to be the feeder services for all this information. These companies built and are continuing to build huge server farms, placed in rows and rows of racks to service billions of requests a day. In addition to internal private corporate networks, a new type of communications emerged, allowing companies to communicate across the public Internet, with technologies to provide various levels of security.

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(CH2)3-Si(OEt)3

(3.2.30)

(CH2)3-Si(OEt)3

[HRed ]

The ubiquity of end users having their own computers on their desks changed the way businesses operate. However, it quickly became clear that managing all of the often geographically dispersed systems was a nightmare. Backing up all the information on these systems alone was an insurmountable task. So began efforts at recentralizing operations. It started with the business-critical servers and applications, then moved to critical business information and associated storage and, with advancements in management software, moved to recentralizing the systems themselves or at least the management of those systems to avoid loss of productivity or data at the remote locations. Throughout the 1980s and 1990s, waves of recentralization and decentralization occurred. When the Internet bubble burst in the late 1990s, the resulting economic downturn forced corporate IT management to begin slashing operational budgets. IT was responsible for managing large infrastructures based on a model where every server ran only one application (e.g., Exchange, SQL, etc.). Often

(3.2.31) where EOr is the formal potential. The concentration of the anion of the reduced form is substituted from the equation for the dissociation constants and from the equation for the overall concentration of hydroquinone, c Red , , = [H2Red] + [HRecT] + [Red2"]

(CH2)3-Si(OEt)3

\n([H]

2

(CH2)3-Si(OEt)3

(3.2.33)

(CH2)3-Si(OEt)3

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