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165 101 Concentration Fig. 1.2 Dependence of the dissociation degree a of a week electrolyte on molar concentration c for different values of the apparent dissociation constant K' (indicated at each curve)

Figure 13.2. UV/visible absorption spectra for TSUA in EtOH (top) and BSUA in THF (bottom).

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In the limiting case (readily obtained by differentiation of the numerator and denominator with respect to c) it holds that ar- l for c 0, i.e. each weak electrolyte at sufficient dilution is completely dissociated and, on the other hand, for sufficiently large c, cv >0, i.e. the highly concentrated electrolyte is dissociated only slightly. The dependence of a on c is given in Fig. 1.2. For strong electrolytes, the activity of molecules cannot be considered, as no molecules are present, and thus the concept of the dissociation constant loses its meaning. However, the experimentally determined values of the dissociation constant are finite and the values of the degree of dissociation differ from unity. This is not the result of incomplete dissociation, but is rather connected with non-ideal behaviour (Section 1.3) and with ion association occurring in these solutions (see Section 1.2.4). Arrhenius also formulated the first rational definition of acids and bases: An acid (HA) is a substance from which hydrogen ions are dissociated in solution: A base (BOH) is a substance splitting off hydroxide ions in solution:

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This appendix includes vendor and product information on blade server systems, virtualization software, and other related hardware and software products, including blade switches, management software, power and cooling products, and processor chipsets. The information included in this appendix has been provided directly by the vendors and does not include any analysis from the authors. More-detailed discussions and analysis of selected products are included in 16, Key Vendor and Product Analysis. For updated information on any of these vendors and their products, refer to the individual vendor websites.

is energetically favorable, thus providing the main intermolecular interaction during the crystallization process. This is direct evidence of the hydrogen-bonding capability of urea ligands. The azobenzene ligands are all in the trans conformation. Azobenzene planes in M1 and M2 are parallel to those in M4 and M3, respectively, with the angle of the two sets of planes at 81.21. The supplementary crystallographic data (CCDC 192903) for TSUA compound can be obtained free of charge through www.ccdc.cam.ac.uk/conts/retrieving.html. The crystallography data of the TSUA cis crystals were not resolved because of dif culty in obtaining single TSUA cis crystals.

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This approach explained many of the properties of acids and bases and many processes in which acids and bases appear, but not all (e.g. processes

Figure 13.3. Unit cell structure of TSUA. Dotted bonds are H-bonds between two urea groups in the unit cell. Source: From Liu et al., 2003b. Reprinted with permission.

13 in non-aqueous media, some catalytic processes, etc.). It has a drawback coming from the attempt to define acids and bases independently. However, as will be seen later, the acidity or basicity of substances appears only on interaction with the medium with which they are in contact.

Company name: Dell Inc. HQ address: 1 Dell Way Round Rock, TX 78682 Contact info: 1-800-WWW-DELL Website: www.dell.com Date founded: 1984 Dates of blade system and/or virtualization SW FCS:

References Dunsch, L., Geschichte der Elektrochemie, Deutscher Verlag fur Grundstoffindustrie, Leipzig, 1985. Ostwald, W., Die Entwicklung der Elektrochemie in gemeinverstdndlicher Darstellung, Barth, Leipzig, 1910. 1.2 1.2.1 Structure of Solutions Classification of solvents

The as-synthesized pure BSUA is a yellow needlelike powder with a melting point of 2251C and a decomposition temperature of 2281C. Thin lms were prepared by dissolution of the as-synthesized BSUA in THF followed by casting on a silicon substrate. Slower evaporation of this same solution produced a shiny yellowfaceted solid. These samples showed some interesting properties. The ability of BSUA to both photoisomerize and self-assemble allows it to adopt various molecular-level mesoscale and macroscale structures. At the molecular level, exposure to UV light transforms the trans isomer to the cis isomer, whereas exposure to longer wavelength light or heat causes the reverse cis-trans isomerization. On the mesoscale level, hydrogen bonding between the bisurea groups and p p stacking interactions between azobenzene bridges cause supramolecular assembly into well-de ned lamellar structures. On the macroscale, the supramolecular structures exhibit multiple morphologies, sheetlike, twisted ropelike, or ribbonlike structures (Fig. 13.4).

Number of employees: ~75,000 Revenue and customer base: 57.4 billion for previous four quarters ending in Q2FY07; #25 on the Fortune 500 Industry awards/recognition: Numerous; please see dell.com for the latest. Targeted markets: Dell products are factory-customized for almost any solution. Types of solutions offered: Blade servers PC blades/thin clients Processor chipsets Blade switch modules High-speed interconnects (InfiniBand, 10 GigE, FC) Virtualization software Clustering software Management software Power & cooling solution

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